Christine Duval

Associate Professor
Department of Chemical and Biomolecular Engineering
Case School of Engineering
Member
Cancer Imaging Program
Case Comprehensive Cancer Center

Research Information

Research Interests

We develop advanced materials and processes to separate f-elements (lanthanides and actinides) with applications in recycling used nuclear fuel, nuclear medicine, and recovering rare earth elements from waste streams. For more information on current projects, visit our research website.

Awards and Honors

Presidential Early Career Award for Scientists and Engineers (PECASE)
2025
CSE Research Award
2024
Crain's Cleveland Business 40 under 40
2024
CWRU John S. Diekhoff Award for Distinguished Graduate Student Mentoring
2024
NAE US Frontiers in Engineering
2023
NSF CAREER award
2023
NAMS Young Membrane Scientist Award
2022
CSE Graduate Teaching Award
2022
DOE Early Career Research Award
2020
CSE Undergraduate Teaching Award
2020

Publications

Check out google scholar for our most up to date publication list.

2025

  • Monge Neria, R; Zeeshan, M; Kapoor, A; Gurkan, B; Duval, CE; Saylor, RA; Kisley, L. “Super-resolution imaging reveals resistance to mass transfer in functionalized stationary phases.” Accepted and in press.

2024

  • Kent, K; Dean-Kersten, W; Duval, CE; Servis, A. “Distributed Sustainable Metals Production: Opportunities for Intensifying Separations & Alternative Feedstocks” Current Opinion in Chemical Engineering. https://doi.org/10.1016/j.coche.2024.101075
  • Suresh, P; Johnson, L; Duval, CE. “Membrane adsorbers with copolymer coatings for the separation of actinides from lanthanides (UO22+ and La3+).” ACS Industrial & Engineering Chemistry Research. 10.1021/acs.iecr.4c03288
  • Johnson, L; Schneider, B; Mithaiwala, H ; Green, MD; Renner, JN; Duval, CE. “Electrospun Membranes Modified with Lanmodulin-Derived Peptides for Lanthanide Adsorption.” ACS Applied Engineering Materials, 2024, 2, 10, 2441-2453. https://doi.org/10.1021/acsaenm.4c00510
  • Kersten, B; Hawthorne, K; Williamson, M; Akolkar, R; Duval, CE. “Insight into electrodeposition inefficiencies of Am from AmCl3-LiCl-KCl through diffusion-reaction modeling, voltammetry and potentiometry.” Journal of the Electrochemical Society. https://doi.org/10.1149/1945-7111/ad80d2 
  • Verma, G; Hostert, J; Summerville, S; Robang, AS; Paravatsu, A; Getman, R; Duval, CE; Renner, JN. “Investigation of Rare Earth Element Binding to a Surface-Bound Affinity Peptide Derived from EF-Hand Loop I of Lanmodulin.” ACS Applied Materials & Interfaces, 2024, 16, 13, 16912-16926. https://doi.org/10.1021/acsami.3c17565

2023

  • Kersten, B; Akolkar, R; Duval, CE. “An electrochemical technique for sensing uranium adsorption.“ Analytica Chimica Acta. 2023, 1284, 34200-342003. https://doi.org/10.1016/j.aca.2023.342003
  • Sepesy, M; Banik, T; Scott, J; Johnson, A; Schneider, BL; Sibley, MM; Duval, CE. “Chemically stable, styrenic electrospun membranes with tailorable surface chemistry.” Membranes.13(11), 870; “Women in Membrane Science” issue edited by Isabel Escobar. https://doi.org/10.3390/membranes13110870
  • Hostert, JD; Sepesy, M; Renner, JN; Duval, CE. “Clickable polymer scaffolds enable Ce recovery with peptide ligands.” Soft Matter, 2023, 19, 2823-2831. https://doi.org/10.1039/D2SM01664H

2022

  • Kersten, B; Hawthorne, K; Williamson, M; Akolkar, R; Duval, CE. “Synthesis of americium trichloride via chlorination of americium oxide using zirconium tetrachloride in LiCl-KCl molten salt.” J. Radioanalytical and Nuclear Chemistry, 2022, 331, 4913-4918. https://doi.org/10.1007/s10967-022-08527-3
  • Suresh, P; Che, A; Yu, M; Pataroque, K; Kulbacki, D; Duval, CE. “Including non-binding ‘spacer’ monomers in polymeric phosphonate ligands can tune ligand-ion affinity for rare earth element, La.” ACS Applied Polymer Materials. 2022, 4, 9, 6710-6722. https://doi.org/10.1021/acsapm.2c01065
  • Sepesy, M; Fugate, B; Duval, CE. “Amine-functionalized membranes to capture copper from acidic solutions.”  ACS Applied Polymer Materials, 2022. Special Issue: Early Career Forum (invited). https://doi.org/10.1021/acsapm.1c01512

2021

2020

  • Suresh, P; Duval, CE. “Poly(acid) grafted membranes to sequester uranium from seawater.” Industrial & Engineering Chemistry Research, 2020, 59, 26, 12212-12222. https://doi.org/10.1021/acs.iecr.0c01090
  • Yu, M; Renner, JN; Duval, CE. “A lysine-modified polyethersulfone (PES) membrane for lanthanide recovery.” Frontiers in Chemistry, 2020. Special Edition for Women in Science: Chemistry. https://doi.org/10.3389/fchem.2020.00512

2019

  • Duval, CE; Hardy, W; Pellizzeri, S; DeVol, TA; Husson, SM. “Phosphonic acid and alkyl phosphate-derivitized resins for the simultaneous concentration and detection of uranium in environmental waters” Reactive and Functional Polymers, 2019 (137), 133-139. https://doi.org/10.1016/j.reactfunctpolym.2019.01.015

2018

  • Duval, CE; Darge, AW; Ruff, CL; DeVol, TA; Husson, SM. “Rapid sample preparation for alpha spectroscopy with ultrafiltration membranes” Analytical Chemistry. 2018 (90) 6, 4144-4149. https://doi.org/10.1021/acs.analchem.8b00135

Prior to CWRU

  • Duval, CE; DeVol, TA; Husson, SM. "Extractive scintillating polymer sensors for trace-level detection of uranium contaminated ground water" Analytica Chimica Acta. 2016 (947), 1-8. *Featured on cover https://doi.org/10.1016/j.aca.2016.09.029
  • Thies, S; Duval, CE; DeVol, TA; Husson, SM. “Creating Monodisperse Polymer Microspheres Using Membrane Emulsification” Journal of Applied Polymer Science. 2016 (44593), 1-9. https://doi.org/10.1002/app.44593
  • Duval, CE; DeVol, TA; Wade, EC; Seliman, AF; Bliznyuk, VN; Husson, SM. "Stability of polymeric scintillating resins developed for ultra-trace level detection of alpha- and beta-emitting radionuclides" Journal of Radioanalytical and Nuclear Chemistry. 2016 310 (2), 583-588. https://doi.org/10.1007/s10967-016-4913-3
  • Duval, CE; DeVol, TA; Husson, SM. “Evaluation of resin radius and column diameter for the implementation of extractive scintillating resin in flow-cell detectors” Journal of Radioanalytical and Nuclear Chemistry. 2016 (307), 2253-2258.
  • Blyzniuk, VN; Duval, CE; Apul, OG; Seliman, AF; Husson, SM; DeVol, TA. “High porosity scintillating polymer resins for ionizing radiation sensor applications” Polymer. 2015 (56), 271-279.
  • D. Kim, D. Donahue, B. Kuncharam, C. Duval and B. Wilhite, “Toward an integrated ceramic micro-membrane network:  Effect of Ethanol Reformate on Palladium Membranes” Industrial & Engineering Chemistry Research. 2010 49 (21), 10254-10261.

Education

PhD
Chemical Engineering
Clemson University
2017
BS
Chemical Engineering
University of Connecticut
2011